Is it possible to get li-ion battery charge level?

There is some battery code here, that can likely be adapted. I’m using it on my Tufty.
That being said, I “think” there are some complications when you try to run it on a Pico W based device.

pimoroni-pico/micropython/examples/pimoroni_pico_lipo at main · pimoroni/pimoroni-pico (github.com)